|
Abstract
We study the packing of spherocylindrical molecules inside a freely
rotating right circular cylindrical domain at the liquid-gas interface.
The analysis is made under the assumption that the molecules of the domain
are rigid and close packed, and that they are parallaly oriented. Their
common inclination relative to the normal to the interface is completely
arbitrary. This result is essential when attempting to model a Langmuir
film. As a first application we obtain an expression for the packing
fraction, as a function of domain size, direction of inclination, and angle
of inclination. The expression is exact for all domain sizes, all
directions, and all angles.
|